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Malathion is a nonsystemic, wide-spectrum organophosphate insecticide.

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SKU: RXSOL-94-9402-250 Category:
   

Description

Malathion is a nonsystemic, wide-spectrum organophosphate insecticide. It was one of the earliest organophosphate insecticides developed. Malathion is suited for the control of sucking and chewing insects on fruits and vegetables, and is also used to control mosquitoes, flies, household insects, animal parasites (ectoparasites), and head and body lice. Malathion may also be found in formulations with many other pesticides. Malathion has been effectively used for mosquito control around the world for more than 60 years. As an organophosphate, it is in a different class of chemistry as opposed to all pyrethroid-class insecticides.

Application:

Dose:

GENERAL DIRECTIONS FOR USE

Pesticides Malathion 96 ULV is used undiluted in specially designed aircraft or ground equipment capable of applying ultra low volumes for control of the insects indicated.

PERSONAL PROTECTIVE EQUIPMENT

For all ULV products used for agricultural crops (food and feed crops) and wild host plants in non-agricultural land, the following is required: For ULV Ground Applications: Limit the amount of active ingredient handled per day to 95 kg per person (approx. 70 ha at a rate of 1375 g a.i./ha, and 150 ha at a rate of 653 g a.i./ha). Wear cotton coveralls over long pants, long sleeved shirts, and chemical-resistant gloves during mixing/loading, application, clean-up and repair. For ULV Aerial Applications: Limit the amount of active ingredient handled per day to 1125 kg per person (approx. 820 ha at a rate of 1375 g a.i./ha, and 1700 ha at a rate of 653 g
a.i./ha).
Wear cotton coveralls over long pants, long sleeved shirts, and chemical-resistant gloves during mixing/loading, clean-up and repair. DO NOT contaminate irrigation or drinking water supplies or aquatic habitats by cleaning of equipment or disposal of wastes. Field sprayer application: DO NOT apply during periods of dead calm. Avoid application of this product when winds are gusty
 

Aerial application:

DO NOT apply when wind speed is greater than 16 km/h at flying height at the site of application.

Note:

Use Precautions



Apply only when meteorological conditions at the treatment site allow for complete and even crop coverage. Apply only under conditions of good practice specific to aerial application as outlined in the National Aerial Pesticide Application Manual, developed by the Federal/Provincial/Territorial Committee on Pest Management and Pesticides.

Exercise special care: Use the correct equipment for the job. Use sufficient water for even distribution. Use low nozzle pressures (Below 300 kPa). Use appropriate buffer zones around sensitive areas such as water, urban and residential areas. Do not spray in winds exceeding 10-15 km per hour. Do not spray in dead calm near sensitive plants or when wind velocity and direction pose a risk of spray drift. A cloud of suspended droplets may drift onto sensitive plants when the wind comes up. Spray only when the wind is blowing away from a sensitive crop, shelter belt or garden.



Operator Precautions

Do not allow the pilot to mix chemicals to be loaded onto the aircraft. Loading of premixed chemicals with a closed system is permitted. It is desirable that the pilot have communication capabilities at each treatment site at the time of application. The field crew and the mixer/loaders must wear chemical resistant gloves, coveralls and goggles or face shield during mixing/loading, cleanup and repair. Follow the more stringent label precautions in cases where the operator precautions exceed the generic label recommendations on the existing ground boom label.

Additional information

MSDS

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Product Name          </td>
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Pesticides Malathion</td>
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Part Number</td>
<td>
RXSOL-94-9402-250</td>
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<p>
<strong>Company Details:<br />
RX MARINE INTERNATIONAL<br />
105, A wing , BSEL , TECH PARK.<br />
VASHI ,NEW BOMBAY 400703 INDIA</strong></p>
<p>
<strong>Branch : Sikka, Kandla,  Dahej , Hazira, JNPT, Goa, Mngalore, Cochin, Tuticorin,Chennai, Kakinada,Vizag,  Paradip, Haldia, Kolkata,Fujairah</strong></p>
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Phone</td>
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+91 22 27815540 / 27815542</td>
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Fax</td>
<td>
+91 22 2781 1318 :::AOH :0091 9821214367</td>
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Email</td>
<td>
<a href="mailto:mail@rxmarine.com">123@rxmarine.com</a></td>
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Website</td>
<td>
<a href="http://www.rxmarine.com/">www.rxmarine.com</a></td&gt;
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Name     of        Substance                         </td>
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        Cas Number      </td>
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       Weight %      </td>
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<td>
Malathion</td>
<td>
       121-75-5 </td>
<td>
        1180g/L</td>
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<td>
HAZARD CLASSIFICATION</td>
<td>
Xn- Harmful RISK PHRASES: R22 – Harmful if swallowed SAFETY PHRASES: S24– After contact with skin. National Poisons Information Centre 131 126.</td>
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<td>
RISK PHRASES</td>
<td>
R22 – Harmful if swallowed</td>
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<td>
SAFETY PHRASES</td>
<td>
S24– After contact with skin. National Poisons Information Centre 131 126.</td>
</tr>
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<td>
GENERAL</td>
<td style="text-align: justify;">
No adverse health effects are expected when the product is used in accordance with label directions. If mishandled (excessive exposure) may cause organophosphorus cholinesterase inhibition. Poisoning symptoms include headaches, dizziness, nausea, diarrhoea, incoordination, muscle twitching, tremors, abdominal cramps, tightness in chest, sweating, blurred vision, salivation, excessive urination and convulsions.<br />
ACUTE</td>
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<td>
SWALLOWED</td>
<td style="text-align: justify;">
The acute oral toxicity is Moderate. Oral LD50 (rat) 2800mg/kg (Malathion).<br />
For product Oral LD50 (rat) 2947mg/kg</td>
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<td>
EYE</td>
<td>
Moderate eye irritant.</td>
</tr>
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<td>
SKIN</td>
<td style="text-align: justify;">
The acute dermal toxicity is low, however repeated exposure may result in absorption of harmful amounts. Repeated skin contact may cause allergic reactions. Dermal LD50 (rabbit) 4100mg/kg (Malathion).<br />
For product LD50 > 4315mg/kg.</td>
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<td>
INHALED</td>
<td style="text-align: justify;">
The acute inhalation toxicity is moderate. Excessive exposure to dust may be harmful. Prolonged exposure to the dust may cause eye and respiratory irritation, dizziness and headaches. Inhalation LD50 (rat) = 5.2 mg/m 3 (4 hours) (Malathion).</td>
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<td>
CHRONIC</td>
<td style="text-align: justify;">
Repeated exposure may cause cholinesterase inhibition. Avoid prolonged or repeated skin contact as the solvent in the product may cause dermatitis.</td>
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<td>
GENERAL</td>
<td style="text-align: justify;">
In every case of suspected poisoning contact a doctor or a Poisons Information Centre immediately.</td>
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<tr>
<td>
SWALLOWED</td>
<td style="text-align: justify;">
Seek medical attention immediately. If more than 15 minutes from medical assistance, give one atropine tablet every 5 minutes until dryness of mouth occurs then seek medical attention immediately. NOTE: Do not give fluids/tablets if patient is unconscious or convulsing.</td>
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<td>
Eye Contact            </td>
<td style="text-align: justify;">
Hold eyelids open and flush eyes with water for at least fifteen minutes. Seek medical attention immediately.</td>
</tr>
<tr>
<td>
SKIN</td>
<td>
<div style="text-align: justify;">
Immediately remove contaminated clothing and wash skin thoroughly with soap and water for at least fifteen minutes. If symptoms of poisoning occur give atropine tablets as above and seek medical attention immediately.</div>
</td>
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<td>
INHALED</td>
<td style="text-align: justify;">
Immediately remove patient to fresh air. If difficulty in breathing is experienced, give oxygen and artificial<br />
respiration if necessary. If symptoms of poisoning occur, seek medical assistance immediately.</td>
</tr>
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<td>
FIRST AID FACILITIES</td>
<td style="text-align: justify;">
Soap, water, Ipecac Syrup APF, Atropine tablets.</td>
</tr>
<tr>
<td>
ADVICE TO DOCTOR</td>
<td style="text-align: justify;">
Malathion is a cholinesterase inhibitor. Preferred antidote: atropine by injection or atrovent/ipratropium by airway puff. This product contains petroleum type solvents and the benefits of induced vomiting must be weighed against possibility of chemical poisoning.</td>
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Flammability</td>
<td>
Flammable</td>
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<td>
Special Hazards from Substance</td>
<td>
Reacts violently with water.</td>
</tr>
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<td>
Extinguishing Media</td>
<td style="text-align: justify;">
Do NOT use water — use CO2, sand, or extinguishing powder.</td>
</tr>
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<td>
Special Fire Fighting Procedures</td>
<td style="text-align: justify;">
Use full-face, self-contained breathing apparatus with full protective clothing to prevent contact with skin and eyes. See Section 10 for decomposition products.</td>
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If Material is Released / Spilled</td>
<td style="text-align: justify;">
Use appropriate personal protective equipment. Avoid dust formation. Avoid breathing dust,vapors, mist, or gas. Isolate spill area and provide ventilation. Evacuate personnel to safe areas. Vacuum up spill using a high efficiency particulate absolute (HEPA) air filter and place in a closed container for disposal.</td>
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<td>
Environmental Precautions</td>
<td>
Isolate runoff to prevent environmental pollution.</td>
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SPILLAGE</td>
<td style="text-align: justify;">
Wear appropriate clothing while cleaning up spill (see Personal Protection). Extinguish any ignition sources. Prevent entry into drainage systems, waterways, rivers, etc. Apply absorbent material such as sand, earth or attapulgite to contain the spill. Sweep up the material when absorption is complete. Wash contaminated surfaces with a mild bleach solution (sodium hypochlorite).</td>
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<td>
Storage Conditions.</td>
<td style="text-align: justify;">
Store closed in the original container, in a cool, well dry place out of direct sunlight and out of the reach of children. Do not store prepared spray. Only mix what is required.TRANSPORT Product is classified as a dangerous good in accordance with the EC Regulation.  </td>
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<td>
DISPOSAL</td>
<td style="text-align: justify;">
Disposal of contaminated material must be done in accordance with State and/or Local regulations. Triple rinse containers with water and add rinsings to tank mix. Destroy empty containers by breaking, crushing or puncturing them. Dispose of the empty containers at a local authority landfill. Do not burn empty containers or product. Do not allow chemical containers, spray or washings to contaminate drains, sewers,<br />
streams, ponds or any waterway.</td>
</tr>
<tr>
<td>
FIRE/EXPLOSION HAZARD</td>
<td style="text-align: justify;">
Hazchem: 2WE Malathion will decompose rapidly when heated to temperatures above 100 OC. Explosion may result under certain circumstances. If involved in a fire, volatile, toxic, malodorous and flammable compounds will be formed HAZARDOUS DECOMPOSITION PRODUCTS: If involved in a fire, thermal decomposition products may include dimethyl sulfide, sulphur dioxide, carbon monoxide, carbon dioxide, phosphorous pentoxide and nitrogen oxides. If store for long periods above 55 OC, toxic degradation products such as malaoxon and isomalathion may be formed.</td>
</tr>
<tr>
<td>
FIRE FIGHTING EQUIPMENT:</td>
<td style="text-align: justify;">
Foam, carbon dioxide (CO2), or dry chemical extinguishers may be used. Run-off must be contained. Full personal protective equipment, including self contained breathing apparatus, is required.</td>
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Engineering Controls</td>
<td style="text-align: justify;">
Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits.</td>
</tr>
<tr>
<td>
Eye Protection</td>
<td>
Safety glasses</td>
</tr>
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<td>
Protective Gloves</td>
<td>
<p>
Compatible chemical-resistant gloves</p>
</td>
</tr>
<tr>
<td>
Other Protective Clothing</td>
<td>
Lab coat</td>
</tr>
<tr>
<td>
Respiratory Equipment</td>
<td>
NIOSH approved respirator, as conditions warrant</td>
</tr>
<tr>
<td>
Work/Hygienic/Maintenance Practice</td>
<td style="text-align: justify;">
Do not take internally<br />
Facilities storing or utilizing this material should be equipped with an eyewash and a safety shower. Wash thoroughly after handling. No data available.</td>
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Apperance and Odour</td>
<td>
Straw to amber coloured liquid with a slightly aromatic odor.</td>
</tr>
<tr>
<td>
Specific Gravity</td>
<td>
 1.23 g/ml</td>
</tr>
<tr>
<td>
Bulk Density</td>
<td>
 1.23 kg/L</td>
</tr>
<tr>
<td>
Vapor Pressure</td>
<td>
3.4 x 10 -6 mm/hg @ 25oc (77o F)</td>
</tr>
<tr>
<td>
Boilling Point </td>
<td>
>300oF/>148.9oC.</td>
</tr>
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<td>
Percent VolatileL</td>
<td>
Not Established</td>
</tr>
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<td>
Evaporation Rate</td>
<td>
<1</td>
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Reactivity                                  </td>
<td>
No Data Available</td>
</tr>
<tr>
<td>
Stability</td>
<td>
Stable </td>
</tr>
<tr>
<td>
Condition to Avoid </td>
<td>
No Data Available</td>
</tr>
<tr>
<td>
Incompatible Materials</td>
<td>
Strong Oxidizing Agent</td>
</tr>
<tr>
<td>
Hazardous Decomposition Products</td>
<td>
Carbon Dioxide, Sulfer Oxides</td>
</tr>
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<td>
Toxicological Effects</td>
<td>
Malathion – Toxicity Data: Oral LDLO (woman): 8 mL/kg; Oral LDLO (man):<span style="font-family: arial, verdana, sans-serif; font-variant-numeric: normal; font-variant-east-asian: normal;"> 471 </span>mg/kg; Oral LD50 (rat): 290 mg/kg; Intraperitoneal LD50 (rat): 250 mg/kg; Oral LD50 (mouse): 190 mg/kg; Intraperitoneal LD50 (mouse): 193 mg/kg; Subcutaneous LD50 (mouse): 221 mg/kg<span style="font-family: arial, verdana, sans-serif; font-variant-numeric: normal; font-variant-east-asian: normal;">;</span></td>
</tr>
<tr>
<td>
Chronic Toxicological</td>
<td style="text-align: justify;">
Malathion – Investigated as an agricultural chemical, mutagen, reproductive effector, and<br />
tumorigen</td>
</tr>
<tr>
<td>
Effect</td>
<td style="text-align: justify;">
Only select Registry of Toxic Effects of Chemical Substances (RTECS) data is presented here. See actual entry in RTECS for complete information. Ethanol RTECS Number: WM8400000</td>
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<td>
Toxicity</td>
<td style="text-align: justify;">
Avoid release into the environment. Runoff from fire control or dilution water may cause pollution<span style="font-family: arial, verdana, sans-serif; font-variant-numeric: normal; font-variant-east-asian: normal; text-align: left;">.</span></td>
</tr>
<tr>
<td>
Ecological Information</td>
<td>
Persistence and No data available</td>
</tr>
<tr>
<td>
Bioaccumulative potential    </td>
<td>
No Data Available.</td>
</tr>
<tr>
<td>
Mobility in Soil</td>
<td>
No data available.</td>
</tr>
<tr>
<td>
Results of PBT and vPvB assessment:</td>
<td>
No data available</td>
</tr>
<tr>
<td>
Other adverse effects</td>
<td>
No data available</td>
</tr>
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<td>
Remarks</td>
<td style="text-align: justify;">
Please consider the relevant national or regional provisions. Waste shall be separated into the categories that can be handled separately by the local or national waste management facilities.</td>
</tr>
<tr>
<td>
Waste Disposa</td>
<td style="text-align: justify;">
The product should not be allowed to enter drains, water courses or the soil. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility.Product may be burned in an incinerator equipped with afterburner and scrubber. Excess and expired materials are to be offered to a licensed hazardous material disposal company.</td>
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 </p>
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<p>
ADR/RID</p>
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<td>
UN number                   </td>
<td>
3082</td>
</tr>
<tr>
<td>
UN proper shipping name</td>
<td>
Environmentally hazardous substance liquid, (Malathion)</td>
</tr>
<tr>
<td>
DANGEROUS GOODS CLASS</td>
<td>
Class 9 Miscellaneous</td>
</tr>
<tr>
<td>
Packing Group</td>
<td>
III</td>
</tr>
<tr>
<td>
Sub Classes</td>
<td>
None Allocated</td>
</tr>
</tbody>
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<p>
IMDG</p>
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<tbody>
<tr>
<td>
UN number                   </td>
<td>
3082</td>
</tr>
<tr>
<td>
UN proper shipping name</td>
<td>
Environmentally hazardous substance liquid, (Malathion)</td>
</tr>
<tr>
<td>
DANGEROUS GOODS CLASS</td>
<td>
Class 9 Miscellaneous</td>
</tr>
<tr>
<td>
Packing Group</td>
<td>
III</td>
</tr>
<tr>
<td>
Sub Classes</td>
<td>
None Allocated</td>
</tr>
</tbody>
</table>
<p>
IATA</p>
<p>
 </p>
<table border="0" cellpadding="1" cellspacing="1">
<tbody>
<tr>
<td>
UN number                   </td>
<td>
3082</td>
</tr>
<tr>
<td>
UN proper shipping name</td>
<td>
Environmentally hazardous substance liquid, (Malathion)</td>
</tr>
<tr>
<td>
DANGEROUS GOODS CLASS</td>
<td>
Class 9 Miscellaneous</td>
</tr>
<tr>
<td>
Packing Group</td>
<td>
III</td>
</tr>
<tr>
<td>
Sub Classes</td>
<td>
None Allocated</td>
</tr>
</tbody>
</table>
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<td>
<p>
Addition Transport</p>
</td>
<td style="text-align: justify;">
Transport in accordance with local, state, and federal regulations.</td>
</tr>
<tr>
<td style="text-align: justify;">
Information</td>
<td style="text-align: justify;">
When sold in quantities of less than or equal to 1 mL, or 1 g, with an Excepted Quantity Code of E1, E2, E4, or E5, this item meets the De Minimis Quantities exemption, per IATA 2.6.10. Therefore packaging does not have to be labeled as Dangerous Goods/Excepted Quantity.</td>
</tr>
<tr>
<td>
Regulatory Information </td>
<td>
This SDS was prepared in accordance with 29 CFR 1910.1200 and Regulation (EC)</td>
</tr>
</tbody>
</table>
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<p style="text-align: justify;">
 </p>
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<td style="text-align: justify;">
Other Information </td>
<td style="text-align: justify;">
The information above is believed to be accurate and represents the  best information   currently    available  to us.  However,   we   make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and  we assume  no liability resulting from its use. Users should make  their  own  investigations  to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International  has been advised of the possibility of such damages.</td>
</tr>
</tbody>
</table>

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