Product NamePHTHALIC ANHYDRIDE
Part NumberRXSOL-19-1612-025
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Phone+91 22 65113333 / 5555 / 9999
Fax+91 22 2781 1318 :::AOH :0091 9821214367
Email123@rxmarine.com
Websitewww.rxmarine.com
Name of Substance Cas NumberEC NumberWight %
Phthalic Anhydride85-44-9201-607-5 99.8-100%
Maleic Anhydride108-31-6203-571-6 0.01 - 0.05%
SignalWord Danger
Hazard StatementsH302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
Precautionary statements - preventionP280 Wear protective gloves.
P280 Wear eye protection.
Precautionary statements - response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P304 + P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Eye Contact
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.
Skin ContactIn case of contact, immediately flushes skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Inhalation:Move to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately if symptoms occur.
Ingestion:Do not induce vomiting. Obtain medical attention.If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration.
Notes to PhysicianTreat symptomatically
Flammability May be combustible at high temperature.
Auto Ignition Temperature570°C
Flash PointClose Cup: 151.67°C.Open Cup: 165°C
Suitable extinguishing mediaWater, Carbon dioxide (CO2), Foam, Dry powder
Hazardous combustion productsForms explosive mixtures with air on intense heating. Risk of dust explosion. Development of hazardous combustion gases or vapours possible in the event of fire.
Fire Fighting Media and InstructionsStay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Further InformationCool closed containers exposed to fire with water spray. Prevent fire extinguishing water from contaminating surface water or the ground water system.
Spillage Use appropriate tools to put the spilled solid in a convenient waste disposal container. Corrosive solid. Poisonous solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal.
Personal ProtectionAdvice for non-emergency personnel: Avoid substance contact. Avoid inhalation of dusts. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8.
Enviromental PrecautionDo not let product enter drains.
Methods and materials for containment and cleaningCover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts.
Handling
Keep locked up.. Keep container dry. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents.
StorageTightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorised persons.
Advice general occupationalAdvice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance.
Engineering ControlUse process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended nexposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal ProtectionEye/face Protection: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin and body protection: Wear appropriate protective gloves and clothing to prevent skin exposure. Respiratory Protection : Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator exposure limits are exceeded or if irritation or other symptoms are experienced.
Exposure LimitTWA: 6.1 (mg/m3) from ACGIH (TLV) [United States] TWA: 6 from ACGIH (TLV) [United States]Consult local authorities for acceptable exposure limits.
Gloves Suit
Form Solid
ColourWhite
OdourCharacteristic
Odor ThresholdNot Applicable
pH2 at 6 g/l 20 °C
Melting Point131 °C (decomposition)
Boiling Point285°C
Flash Point152 °C Method: DIN 51758
Evaporation RateNot Applicable
Flammability (solid, gas)No Data Available
Lower Explosion limits1.7 %(V)
Upper explosion limit10.5 %(V)
Vapour pressure< 0.01 hPa at 20 °C
Vapour Density6.6
Specific Gravity1.527 g/cm³ at 20 °C
Partition coefficient n-octanol/water log Pow: 2.07 (25 °C) (calculated)
Explosive propertiesNot classified as explosive.
SolubilitySoluble in water 6 g/l at 20 °C
Ignition temperature580 °C Method: DIN 51794
Viscosity, dynamicNo information available
Reactivity Risk of dust explosion. Forms explosive mixtures with air on intense heating.
StabilityThe product is chemically stable under standard ambient conditions (room temperature).
Possibility of hazardous reactionViolent reactions possible with:
Strong acids, Organic acids, strong reducing agents, Water, alkali hydroxides, Nitric acid, Alcohols, glycerol, metallic oxides, nitrites, Oxidizing agents, Air metals, (in the presence of atmospheric oxygen and/or moisture)
Conditions to avoidStrong Heating
Incompatible materialsRubber Various Plastic
Hazardous PolymerizationHazardous polymerization does not occur.
Rout Of EntryAbsorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Toxicity to AnimalWARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 1500 mg/kg [Mouse]. Acute dermal toxicity (LD50): >10000 mg/kg [Rabbit]. Acute toxicity of the dust (LC50): >210 mg/m 1 hours [Rat].
Toxic Effects on HumanVery hazardous in case of skin contact (irritant), of ingestion, of inhalation. Hazardous in case of skin contact (corrosive, permeator), of eye contact (corrosive).
Special Remarks on other Toxi Effects on Humans:
Acute Potential Health Effects: Corrosive! If the solid materials is permitted to remain in contact with moist tissues, superficial burns may result. Skin: May cause severe skin irritation witn possible skin burns. If the skin is moist the irritant effects will be greater due to hydrolysis of phthalic acid. Eyes: May cause severe eye irritation with possible eye burns. May cause chemical conjunctivitis and corneal damage. Inhalation: Causes severe respiratory tract irritation with possible chemical burns to the respiratory tract. May cause asthmatic attacks due to allergic sensitization of respiratory tract. May also affect respiration, and liver. Symptoms may include Rhinorrhea, blaody nasal disharge, hoarseness of voice, cough, bronchospasm Ingestion: Causes severe digestive tract irritation iwth possible burns. May cause severe and permanent damage to the digestive tract. Mah cause perforation of the digestive tract. May affect behavior. Chronic Potential Health Effects: Skin: Prolonged or repeated skin contact may cause allergic skin reaction.
Eco ToxicityNot Available
COD and BOD 5Not Available
Products Biodegradation:99 %; 14 d OECD Test Guideline 301E Readily biodegradable.
Mobility in soilNo Information available
Results of PBT and vPvB assessmentPBT/vPvB assessment not available as chemical safety assessment not required/not conducted.
Other adverse effectsAdditional ecological information Biological effects: Harmful effect due to pH shift. Discharge into the environment must be avoided.
Waste treatment MethodWaste material must be disposed of in accordance with the national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself
DOT
UN Number UN 2214
Proper shipping namePHTHALIC ANHYDRIDE
Hazard Class8
Packing groupIII
Special Provisions for TransportNot Classified as Hazardous for Transport
TDG
UN Number UN 2214
Proper shipping namePHTHALIC ANHYDRIDE
Hazard Class8
Packing groupIII
Special Provisions for TransportNot Classified as Hazardous for Transport
IATA
UN Number UN 2214
Proper shipping namePHTHALIC ANHYDRIDE
Hazard Class8
Packing groupIII
Special Provisions for TransportNot available.
IMDG/IMO
UN Number UN 2214
Proper shipping namePHTHALIC ANHYDRIDE
Hazard Class8
Packing groupIII
Special Provisions for TransportNot Classified as Hazardous for Transport
Fedral and State Regulation Connecticut hazardous material survey.: Phthalic anhydride Illinois toxic substances disclosure to employee act: Phthalic anhydride Illinois chemical safety act: Phthalic anhydride New York release reporting list: Phthalic anhydride Rhode Island RTK hazardous substances: Phthalic anhydride Pennsylvania RTK: Phthalic anhydride Minnesota: Phthalic anhydride Michigan critical material: Phthalic anhydride Massachusetts RTK: Phthalic anhydride
Other RegulationOSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
WHMIS (Canada)CLASS D-2A: Material causing other toxic effects (VERY TOXIC). CLASS E: Corrosive solid.
DSCL (EEC) R22- Harmful if swallowed. R26- Very toxic by inhalation. R38- Irritating to skin. R41- Risk of serious damage to eyes. S1/2- Keep locked up and out of the reach of children. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28- After contact with skin, wash immediately with plenty of [***] S36/37- Wear suitable protective clothing and gloves. S39- Wear eye/face protection. S45- In case of accident or if you feel unwell,
HMIS
Health Hazard: 3
Fire Hazard: 1
Reactivity: 1
Personal Protection: E
Fire :
Health Hazard: 3
Fire Hazard: 1
Reactivity: 0
Specific Hazard:
Other Information
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
SURAT CHEMICAL TAG::
Product NameSodium Fluoride
Part NumberRXSOL-19-8203-025
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Phone+91 22 65113333 / 5555 / 9999
Fax+91 22 2781 1318 :::AOH :0091 9821214367
Email123@rxmarine.com
Websitewww.rxmarine.com
Name of Substance Cas NumberEC NumberWight %
Sodium Fluoride7681-49-4231-667-8 100%
Signal Word Danger
Hazard StatementsH301 Toxic if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
EUH032 Contact with acids liberates very toxic gas.
Precautionary statements - preventionP280 Wear protective gloves.
Precautionary statements response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water fo several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310 IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
Eye Contact
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.
Skin ContactIn case of contact, immediately flushes skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Inhalation:Move to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately if symptoms occur.
Ingestion:Do not induce vomiting. Obtain medical attention.If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration.
Notes to PhysicianTreat symptomatically
Flammability Not Flammable
Flash PointNot Applicable
Suitable extinguishing mediaUse extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Hazardous combustion productsNot available
Protective EquipmentUse personal protective equipment.
Specific Hazards Arising from the ChemicalNot combustible. Ambient fire may liberate hazardous vapours. Fire may cause evolution of: Hydrogen fluoride
Special protective equipment for firefightersStay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Spillage
Use appropriate tools to put the spilled solid in a convenient waste disposal container.Poisonous solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed.
Personal ProtectionAdvice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8.
Enviromental PrecautionDo not let product enter drains.
Methods and materials for
containment and cleaningCover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up the affected area. Avoid generation of dust
Handling
Do not ingest. Do not breathe dust. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, metals, acids, alkalis.
StorageTightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorised persons.Protect from moisture. Store away from foodstuffs
Advice on general occupational hygieneAdvice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance.
Engineering ControlUse process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal ProtectionEye/face Protection: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin and body protection: Wear appropriate protective gloves and clothing to prevent skin exposure. Respiratory Protection : Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator exposure limits are exceeded or if irritation or other symptoms are experienced.
Other Protection MeasureHandle in accordance with good industrial hygiene and safety practice.
Exposure LimitTWA: 2.5 (mg/m3) from NIOSH Consult local authorities for acceptable exposure limits
Gloves Suit
Form Crystal / Solid
ColourWhite
OdourOdourless
Odor ThresholdNot Applicable
pH10.2 at 40 g/l 20 °C
Melting Point996 °C (decomposition)
Boiling Point1,695 °C at 1,013 hPa
Flash PointNot Applicable
Evaporation RateNot Applicable
Flammability (solid, gas)No Data Available
Explosive limitsNo Data Available
Vapour pressure1 hPa at 1,077 °C
Vapour DensityNo information available.
Specific Gravity2.8 g/cm3 at 20 °C
Partition coefficientNo data available
Explosive propertiesNone
SolubilitySoluble in water 50 g/l at 20 °C
Ignition temperatureNo information available.
Oxidizing propertiesNone
Reactivity Reacts with acids..
StabilityThe product is chemically stable under standard ambient conditions.
Possibility of hazardous reactionsGenerates dangerous gases or fumes in contact with: acids Possible formation of : Hydrogen Fluoride.
Conditions to avoidStrong Heating
Incompatible materialsReactive with oxidizing agents, metals, acids, alkalis.
Hazardous PolymerizationHazardous polymerization does not occur.
Rout Of EntryInhalation. Ingestion.
Toxicity to AnimalAcute oral toxicity (LD50): 52 mg/kg [Rat].
Toxic Effects on HumanMay cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer).
Special Remarks on other Toxi Effects on Humans:
Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism.
Further InformationAfter absorption: We have no description of any toxic symptoms. Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice.
Systemic effects:
Cardiac irregularities, respiratory arrest, Nausea, Unconsciousness, death The following applies to soluble inorganic fluorides in general: may cause irritations to burns in contact with eyes, skin, mucous membranes. Systemic effect: drop in blood calcium level, agitation, spasms, cardiovascular disorders, CNS disorders. Handle in accordance with good industrial hygiene and safety practice
Eco ToxicityToxicity to fish : LC50 Gambusia affinis (Mosquito fish): 925 mg/l; 96 h (IUCLID). Toxicity to daphnia and other aquatic invertebrates EC50 Daphnia magna (Water flea): 338 mg/l; 48 h (IUCLID)
COD and BOD 5Not Available
Products Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Mobility in soilNo Information available
Results of PBT and vPvB assessmentPBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effectsHazard for drinking water supplies. Discharge into the environment must be avoided.
Waste treatment MethodWaste material must be disposed of in accordance with the national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself.
DOT
UN Number UN 1690
Proper shipping name
SODIUM FLUORIDE, SOLID
Hazard Class6.1
Packing groupIII
TDG
UN Number UN 1690
Proper shipping name
SODIUM FLUORIDE, SOLID
Hazard Class6.1
Packing groupIII
IATA
UN Number UN 1690
Proper shipping name
SODIUM FLUORIDE, SOLID
Hazard Class6.1
Packing groupIII
IMDG/IMO
UN Number UN 1690
Proper shipping name
SODIUM FLUORIDE, SOLID
Hazard Class6.1
Packing groupIII
Fedral and State RegulationCalifornia prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: No products were found. California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: No products were found. Connecticut hazardous material survey.: Sodium fluoride Illinois chemical safety act: Sodium fluoride New York release reporting list: Sodium fluoride Rhode Island RTK hazardous substances: Sodium fluoride Pennsylvania RTK: Sodium fluoride Massachusetts RTK: Sodium fluoride Massachusetts spill list: Sodium fluoride New Jersey: Sodium fluoride New Jersey spill list: Sodium fluoride Louisiana spill reporting: Sodium fluoride.
Other RegulationOSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
WHMIS (Canada)CLASS D-1B: Material causing immediate and serious toxic effects (TOXIC). CLASS D-2B: Material causing other toxic effects (TOXIC).
DSCL (EEC) R25- Toxic if swallowed. R32- Contact with acids liberates very toxic gas. R36/38- Irritating to eyes and skin. S22- Do not breathe dust. S36- Wear suitable protective clothing. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
HMIS
Health Hazard: 2
Fire Hazard: 0
Reactivity: 0
Personal Protection: E
Fire :
Health Hazard: 3
Fire Hazard: 0
Reactivity: 0
Specific Hazard:
Other Information
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
Product NameGLUTARALDEHYDE
Part NumberRXSOL-19-1196-025
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Phone+91 22 65113333 / 5555 / 9999
Fax+91 22 2781 1318 :::AOH :0091 9821214367
Email123@rxmarine.com
Websitewww.rxmarine.com
Name of Substance Cas NumberEC NumberWight %
Glutaraldehyde111-30-8203-856-5 50%
Non Hazardous Ingirdent 50 %
Signal Word Danger
Hazard StatementsH302 + H332 Harmful if swallowed or if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H410 Very toxic to aquatic life with long lasting effects.
EUH071 Corrosive to the respiratory tract
Precautionary statements - preventionP273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
Precautionary statements - responseP301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310 IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
Eye ContactCheck for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately.
Skin ContactIn case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Inhalation:Move to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately if symptoms occur.
Ingestion:Do not induce vomiting. Obtain medical attention.If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
Notes to PhysicianTreat symptomatically
Flammability Non-flammable.
Flash PointNot applicable.
Suitable extinguishing mediaNo information available
Hazardous combustion
productsWhen heated to decomposition, it emits acrid smoke and fumes.
Protective EquipmentUse personal protective equipment.
Specific Hazards Arising from the ChemicalNot considered to be a significant fire risk.
Small SpillageUse appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements
Personal ProtectionAdvice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8.
Enviromental PrecautionDo not let product enter drains.
Methods and materials for
containment and cleaningCover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts
HandlingDo not ingest. Do not breathe dust. Avoid contact with eyes. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing agents, acids.
StorageLight Sensitive. Refrigerate. Store in light-resistant containers. Keep containers tightly closed. Keep containers in a cool, wellventilated area.Packing : Only packagings which are approved (e.g. acc. to ADR) may be used.
Advice on general occupational hygieneAdvice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance.
Engineering ControlProvide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal ProtectionEye/face Protection : Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin and body protection : Wear appropriate protective gloves and clothing to prevent skin exposure. Respiratory Protection : Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator exposure limits are exceeded or if irritation or other symptoms are experienced.
Other Protection MeasureHandle in accordance with good industrial hygiene and safety practice.
Exposure LimitGlutaraldehyde TWA: 0.2 (ppm) [Australia] TWA: 0.82 (mg/m3) [Australia] TWA: 0.25 CEIL: 0.2 (ppm) from NIOSH CEIL: 0.2 (ppm) from OSHA (PEL) [United States] TWA: 0.05 STEL: 0.05 (ppm) [United Kingdom (UK)] Consult local authorities for acceptable exposure limits.
Gloves Suit
Form Liquid
ColourClear
OdourPungent
Odor ThresholdNo Information Available
pH3.5 - 4.5
Freezing Point-13 °C
Boiling Point101°C
Flash PointNot Applicable
Evaporation RateNot Applicable
Flammability (solid, gas)No Data Available
Explosive limitsNo Data Available
Vapour pressure21 hPa at 20 °C
Vapour Density0.8
Relative density Information1.10 at 25 °C
Partition coefficientNo data available
Explosive propertiesNone
SolubilitySoluble in water
Ignition temperature275 °C
Recativity Forms explosive mixtures with air on intense heating.
StabilityProduct is stable.
Possibility of hazardous reactionsViolent reactions possible with:Amines, Strong oxidizing agents
Violent polymerisation may be caused by: Strong bases, Strong acids
Conditions to avoidStrong Heating
Incompatible materialsAluminium, various metals, Mild steel
Hazardous PolymerizationHazardous polymerization does not occur.
Rout Of EntryAbsorbed through skin. Eye contact. Inhalation. Ingestion.
Toxicity to AnimalWARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 100 mg/kg [Mouse]. Acute dermal toxicity (LD50): >2500 mg/kg [Rat]. Acute toxicity of the vapor (LC50): 480 mg/m 4 hours [Rat]. 3
Toxic Effects on HumansCARCINOGENIC EFFECTS: Classified A4 (Not classifiable for human or animal.) by ACGIH [Glutaraldehyde]. MUTAGENIC
EFFECTS: Mutagenic for mammalian somatic cells. [Glutaraldehyde]. Mutagenic for bacteria and/or yeast. [Glutaraldehyde].
DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Reproductive system/toxin/male [SUSPECTED]
[Glutaraldehyde]. Contains material which may cause damage to the following organs: blood, the reproductive system, liver,
mucous membranes, spleen, central nervous system (CNS), Urinary system.
Special Remarks on other Toxic Effects on Humans:
Potential Health Effects: Eye: Causes severe eye irritation. May cause eye injury or chemical conjunctivitis. Skin: Causes moderate to severe skin irritation. It may be absorbed through the skin, although poorly. May cause allergic contact dermatitis with itching and skin rash. May cause staining of the skin and nails to a brown or golden brown color. Ingestion: Harmful if swallowed. May cause severe irritation of the digestive tract with burning sensation in the chest, abdominal pain, cramping, vomiting, diarrhea (perhaps bloody diarrhea), vascular collapse, and coma. May also affect liver (increased liver enzymes, liver damage), spleen, blood (normocytic anemia), metabolism (weight loss), behavior (somnolence, excitement, dizziness, lethargy, ataxia, seizures), metabolism (weight loss), urinary system ( abnormal reneal function, anuria) Inhalation: Harmful if inhaled. Can cause respiratory tract irritation and sudden headaches.
Eco ToxicityNot Available
COD and BOD 5Not Available
Products of Biodegradation:No Information available
Mobility in soilNo Information available
Results of PBT and vPvB assessmentSubstance(s) in the mixture do(es) not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII, or a PBT/vPvB assessment was not conducted..
Other adverse effectsDischarge into the environment must be avoided.
Waste treatment MethodWaste material must be disposed of in accordance with the national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself
DOT
UN Number UN1307
Proper shipping nameCORROSIVE LIQUID, N.O.S. (GLUTARDIALDEHYDE
SOLUTION)
Hazard Class8
Packing groupII
TDG
UN Number UN1307
Proper shipping nameCORROSIVE LIQUID, N.O.S. (GLUTARDIALDEHYDE
SOLUTION)
Hazard Class8
Packing groupII
IATA
UN Number UN1307
Proper shipping nameCORROSIVE LIQUID, N.O.S. (GLUTARDIALDEHYDE
SOLUTION)
Hazard Class8
Packing groupII
IMDG/IMO
UN Number UN1307
Proper shipping nameCORROSIVE LIQUID, N.O.S. (GLUTARDIALDEHYDE
SOLUTION)
Hazard Class8
Packing groupII
Fedral and State Regulation Pennsylvania RTK: Glutaraldehyde Florida: Glutaraldehyde Massachusetts RTK: Glutaraldehyde New Jersey: Glutaraldehyde California Director's list of Hazardous Substances: Glutaraldehyde TSCA 8(b) inventory: Glutaraldehyde; Water TSCA 8(a) PAIR: Glutaraldehyde TSCA 8(d) H and S data reporting: Glutaraldehyde: 9/30/91 to 9/30/01
Other RegulationOSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
WHMIS (Canada)CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS D-2B: Material causing other toxic effects (TOXIC). CLASS E: Corrosive liquid.
DSCL (EEC)R36- Irritating to eyes. S2- Keep out of the reach of children. S24/25- Avoid contact with skin and eyes. S46- If swallowed, seek medical advice immediately and show this container or label.
HMIS
Health Hazard: 2
Fire Hazard: 0
Reactivity: 0
Personal Protection: H
Fire :
Health Hazard: 2
Fire Hazard: 0
Reactivity: 0
Specific Hazard: H
Other Information
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
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