Tert BUTYL METHYL ETHER AR 99.5%
RXSOL-60-6605-659
Lab Chemical
Tert BUTYL METHYL ETHER AR 99.5%
Part No. RXSOL-60-6605-659
Tert BUTYL METHYL ETHER AR 99.5%
Price, pack size and lead time on request. Email suratchemical @ gmail.com or call +91 80699 76664.
- Also known as
- Tert BUTYL METHYL ETHER AR 99.5%
- Supplied from
- Bhestan, Surat, Gujarat
- Supply locations
- Tert BUTYL METHYL ETHER AR 99.5% manufacturers, suppliers, exporters in Mumbai, Gandhidham, Kolkata, Varanasi, Visakhapatnam, Chennai, Fujairah, Dubai, Canada BC, Barka, Sohar, Muscat, Oman. Lab chemicals manufacturers, suppliers, exporters in India, UAE Middle East, Barka, Sohar, Muscat, Oman, Canada. Tert BUTYL METHYL ETHER AR 99.5% is available in small packing as well as in bulk. Buy premium quality Tert BUTYL METHYL ETHER AR 99.5% and other lab chemicals from one of the most trusted brands.
Description
tert butyl methyl ether ar 99.5 octane booster in gasoline. It is made from blending chemicals such as isobutylene and methanol, and has been used since the 1980s as an additive for unleaded gasolines to achieve more efficient burning.
Note
The degradation of aqueous methyl tert-butyl ether (MTBE) at relatively high concentrations was investigated by various photo-induced oxidation processes such as UV/H2O2 and UV/TiO2 as well as biological processes and their combination. It was shown that the degradation of MTBE by UV/H2O2 and TiO2 photocatalytic followed a first-order model with apparent rate constant of 1.31×10−1 and 1.21×10−2 min-1, respectively. It was observed that UV/H2O2/TiO2 process did not have any advantages over each of the other processes alone.
Application
MTBE is used as a fuel component in fuel for gasoline engines. It is one of a group of chemicals commonly known as oxygenates because they raise the oxygen content of gasoline.
MSDS
| Product Name | Tert BUTYL METHYL ETHER AR 99.5% |
| Part Number | RXSOL-60-6605-659 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| mail@rxmarine.com | |
| Website | www.rxmraine.com |
| Chemical Name | CAS | EC number | Weight | Formula |
| Tert-Butyl methyl ether | 1634-04-4 | 216-653-1 | <= 100 % | C5H12O |
| Signal Word | Danger |
| Hazard Statements | H225 Highly flammable liquid and vapor. H315 Causes skin irritation. |
| P280 Wear protective gloves.P305 + P351 + P338 | Wear eye protection/ face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| Precautionary statements response | P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use non-sparking tools. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. |
| Classification of the substance or mixture | Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. |
| Supplemental Hazard Statements | None |
| Other hazards | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| General advice | Show this material safety data sheet to the doctor in attendance. |
| If inhaled | After inhalation: fresh air. |
| Eye Contact | After eye contact: rinse out with plenty of water. Remove contact lenses. |
| Swallowed | After swallowing: caution if victim vomits. Risk of aspiration! Keep airways free. Pulmonary failure possible after aspiration of vomit. Call a physician immediately. |
| Skin Contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. |
| Inhalation | Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary. |
| Ingestion | Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately. |
| Most important symptoms and effects, both acute and delaye | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Flammability | May be combustible at high temperature. |
| Suitable extinguishing media | Carbon dioxide (CO2) Foam Dry powder |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given. |
| Special hazards arising from the substance or mixture | Carbon oxides Combustible. Pay attention to flashback. Vapors are heavier than air and may spread along floors. Development of hazardous combustion gases or vapours possible in the event of fire. Forms explosive mixtures with air at ambient temperatures. |
| Further information | Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
|
Hazardous combustion products |
Fire may cause the evolution of Sulphur oxides, nitrogen oxides. |
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Protective Equipment | Use personal protective equipment. |
| Specific Hazards Arising from the Chemical |
Has a fire-promoting effect due to the release of oxygen. Ambient fire may liberate hazardous vapours. |
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
| Spillage | Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
| Personal Protection | Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. |
| Enviromental Precaution | Do not let product enter drains. Risk of explosion. |
|
Methods and materials for containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area. |
| Advice on safe handling | Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. |
| Advice on protection against fire and explosion | Keep away from open flames, hot surfaces and sources of ignition. |
| Incompatible materials | Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. |
| Hygiene measures | Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
| Precautions for safe handling | For precautions see section 2.2. |
| Conditions for safe storage, including any incompatibilities | Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials. |
| Storage conditions | Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. |
| Storage class | Storage class (TRGS 510): 3: Flammable liquids |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Advice on general occupational hygiene | Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
| Requirements for storage | Keep in cool and store under shade. |
| Application Area | Routes of exposure | Health effect | Value |
| Worker DNEL,acute | Inhalation | Local effects | 357 mg/m3 |
| Worker DNEL, longterm | Inhalation | Systemic effects | 178,5 mg/m3 |
| Worker DNEL, longterm | dermal | Systemic effects | -- |
| Consumer DNEL, acute | Inhalation | Local effects | 214 mg/m3 |
| Consumer DNEL, longterm | inhalation | Local effects | 53,6 mg/m3 |
| Consumer DNEL, longterm | oral | Systemic effects | -- |
Predicted No Effect Concentration (PNEC)
| Compartment | Value |
| Sea water | 0,26 mg/l |
| Fresh water | 5,1 mg/l |
| Sewage treatment plant | 71 mg/l |
| Aquatic intermittent release | 47,2 mg/l |
| Exposure controls | No specific additional engineering controls are required. Provide good natural or artificial ventilation. |
| Engineering Control | Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. |
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
| Body Protection | Flame retardant antistatic protective clothing. |
| Skin protection | This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Nitrile rubber Minimum layer thickness: 0,4 mm Break through time: 120 min Material tested:Camatril® (KCL 730 / Aldrich Z677442, Size M) |
| Respiratory protection | Required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type AX The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. |
| Other Protection Measure | Handle in accordance with good industrial hygiene and safety practice. |
| Control of environmental exposure | Do not let product enter drains. Risk of explosion. |
| Thermal hazards | No data available |
| Physical state | Liquid |
| Colour | Colorless |
| Odour | Characteristic |
| Odor Threshold | Not Applicable |
| pH | No data available |
| Melting Point | 108,6 °C at 1.013 hPa |
| Boiling Point | 55 - 56 °C - lit. |
| Flash Point | 28 °C - closed cup |
| Evaporation Rate | Not Applicable |
| Flammability (solid, gas) | No data available |
| Explosive limits | No Data Available |
| Upper/lower flammability or explosive limits | 8,5 %(V) / 1,6 %(V) |
| Autoignition temperature | 460 °C at 1013,0 hPa - DIN 51794 |
| Decomposition temperature | No data available |
| Vapour pressure | 330 hPa at 25 °C |
| Viscosity, kinematic / dynamic | 0,409 mm2/s at 40 °C/ 0,36 mPa.s at 20 °C |
| Density | 0,74 g/cm3 at 25 °C |
| Relative density | 0,74 at 20 °C |
| Freezing point | No data available |
| Specific Gravity | No data available |
| Partition coefficient | log Pow: 1,06 at 20 °C |
| Explosive properties | No data available |
| Solubility | 42 g/l at 20 °C |
| Ignition temperature | No information available. |
| Particle characteristics | No data available |
| Reactivity | Vapors may form explosive mixture with air. |
| Stability | The product is chemically stable under standard ambient conditions (room temperature) . |
| Possibility of hazardous reactions | Violent reactions possible with: Oxidizing agents Strong acids halogens Strong bases |
| Conditions to avoid | Warming. |
| Incompatible materials | Rubber, various plastics |
| Hazardous Polymerization | In the event of fire: see section 5 |
| Acute toxicity | LD50 Oral - Rat - male and female - > 2.000 mg/kg (OECD Test Guideline 401) Symptoms: Nausea, Vomiting, Pulmonary failure possible after aspiration of vomit., Aspiration may cause pulmonary edema and pneumonitis. LC50 Inhalation - Rat - male and female - 4 h - 85 mg/l - vapor (OECD Test Guideline 403) Symptoms: Possible damages:, mucosal irritations LD50 Dermal - Rat - male and female - > 2.000 mg/kg (OECD Test Guideline 402) |
| Skin corrosion/irritation | Skin - Rabbit Result: Skin irritation - 4 h (OECD Test Guideline 404) Remarks: Drying-out effect resulting in rough and chapped skin. |
| Serious eye damage/eye irritation | Eyes - Rabbit Result: No eye irritation (OECD Test Guideline 405) |
| Respiratory or skin sensitization | Maximization Test - Guinea pig Result: negative (OECD Test Guideline 406) |
| Toxicity to Animal | WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE Acute oral toxicity (LD50): 689 mg/kg [Rat]. |
| Toxic Effects on Human | May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer). |
| Carcinogenicity | Carcinogenicity - No carcinogenic properties suspected. (IUCLID) |
| Germ cell mutagenicity | No data available Test Type: In vitro mammalian cell gene mutation test Test system: Chinese hamster lung cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: negative Test Type: Ames test Test system: Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Test Type: Mutagenicity (mammal cell test): micronucleus. Test system: mouse lymphoma cells Metabolic activation: without metabolic activation Method: OECD Test Guideline 473 Result: negative Test Type: unscheduled DNA synthesis assay Species: Mouse Cell type: Liver cells Application Route: inhalation (vapor) Method: OECD Test Guideline 486 Result: negative Test Type: Micronucleus test Species: Mouse Cell type: Bone marrow Application Route: inhalation (vapor) Method: US-EPA Result: negative Test Type: Mutagenicity (mammal cell test): chromosome aberration. Species: Rat Cell type: Bone marrow Application Route: inhalation (vapor) Method: US-EPA Result: negative Test Type: Transgenic rodent somatic cell gene mutation assay Species: Rat Cell type: Bone marrow Application Route: inhalation (vapor) Method: OECD Test Guideline 488 Result: negative |
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure | No data available |
| Special Remarks on other Toxi Effects on Humans | Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism. |
| Additional Information | RTECS: AF3675000 Gastrointestinal disturbance To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. After uptake of large quantities: muscular symptoms agitation Convulsions Headache Tremors Nausea psychoses |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Repeated dose toxicity - Rat - male and female - Oral - 90 d - NOAEL (No observed adverse effect level) - 3.000 mg/kg Remarks: Subchronic toxicity RTECS: KN5250000 Nausea, Vomiting, Dizziness, Central nervous system depression, Aspiration or inhalation may cause chemical pneumonitis., MTBE (methyl-tert-butyl ether) is reported to metabolize to tert-butyl alcohol and formaldehyde by microsomal demethylation, MTBE (methyl-tertbutyl ether) should be considered a "potential human carcinogen" due to an increase in leydig interstitial cell tumors of testes in male rats and an increase in lymphomas, leukemias, and uterine sarcomas in female rats., In another unpublished study MTBE was shown to be carcinogenic due to "increased incidence of a rare type of kidney tumor" in male rats and an "increase in the incidence of hepatocellular adenomas" in female mice. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. |
| Persistence and degradability | Biodegradability aerobic - Exposure time 28 d Result: 0 % - Not readily biodegradable. (OECD Test Guideline 301D) |
| Bioaccumulative potential | Bioaccumulation Cyprinus carpio (Carp) - 28 d at 25 °C(tert-butyl methyl ether) Bioconcentration factor (BCF): 1,5 |
| Toxicity to fish | Semi-static test LC50 - Menidia beryllina - 574 mg/l - 96 h (OECD Test Guideline 203) |
| Toxicity to daphnia and other aquatic invertebrates | Flow-through test EC50 - Americamysis bahia (Mysid) - 187 mg/l - 96 h (US-EPA OPPTS 850.1035) |
| Toxicity to bacteria | Static test EC10 - Pseudomonas putida - 710 mg/l - 18 h Remarks: (ECHA) |
| Toxicity to algae | Static test IC50 - Pseudokirchneriella subcapitata (green algae) - 491 mg/l - 96 h |
| Products Biodegradation | The methods for determining the biological degradability are not applicable to inorganic substances. |
| Mobility in soil | No Information available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Other adverse effects | No data available |
| Disposal methods | The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems. |
| Contaminated packaging | Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. |
| Waste treatment Method | See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. |
| UN number | ADR/RID:2398 IMDG:2398 IATA:2398 |
| UN proper shipping name | ADR/RID:Methyl tert-butyl ether IMDG:Methyl tert-butyl ether IATA:Methyl tert-butyl ether |
| Transport hazard class(es) | ADR/RID: 3 IMDG: 3 IATA: 3 |
| Packaging group | ADR/RID: II IMDG: II IATA: II |
| Environmental hazards | ADR/RID: No IMDG: No IATA: No |
| Special precautions for user | Tunnel restriction code : (C/E) |
| Further information | Not classified as dangerous in the meaning of transport regulations. |
| Transport in bulk according to IMOinstruments | No data available |
| Inventory status | Components are on the following inventories: Polymaleic acid: - US TSCA, Canadian DSL, EU EINECS, Australian AICS, Korean, Philippine PICCS and Chinese Xi irritant R 36/38 Irritant to eyes & skin R 41 Risk of serious damage to eyes S24/25 Avoid contact with skin and eyes S26/28 In case of contact eyes & skin, rinse with plenty water and seek medical advice Section 312/313: Not listed. Not listed under California proposition 65. |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Safety, health and environmental regulations specific for the product in question | European Inventory of Existing Commercial Chemical Substances (EINECS) -Listed.EC Inventory Listed. United States Toxic Substances Control Act (TSCA) Inventory- Listed. China Catalog of Hazardous chemicals 2015 Not- Listed. New Zealand Inventory of Chemicals (NZIoC)Listed. PICCS -Listed. Vietnam National Chemical Inventory -Listed. IECSC Listed. Korea Existing Chemicals List (KECL) -Listed. |
| National legislation | Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : FLAMMABLE LIQUIDS |
| Other regulations | Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | A Chemical Safety Assessment has been carried out for this substance. |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
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